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Magnetic properties and phase diagram of ZnxNi1-xFe2O4: High-temperature series expansions

Identifieur interne : 000417 ( Main/Exploration ); précédent : 000416; suivant : 000418

Magnetic properties and phase diagram of ZnxNi1-xFe2O4: High-temperature series expansions

Auteurs : M. Hamedoun [Maroc] ; A. Benyoussef [Maroc] ; M. Bousmina [Maroc]

Source :

RBID : Pascal:10-0428997

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Abstract

Using mean field theory and high-temperature series expansions (HTSEs), extrapolated with the Padé approximants method, the effect of Zn doping on magnetic properties of NiFe2O4 ferrite spinel has been studied. The nearest neighbour super-exchange interactions for intra-site (JAA,JBB) and inter-site (JAB) of the ZnxNi1-xFe2O4 ferrites spinels, in the range 0 ≤ x ≤ 1, have been computed using the probability approach, based on Mössbauer data. The paramagnetic Curie-Weiss temperature 0 and the Curie temperature TC are calculated as a function of Zn concentration. The critical exponent γ associated with magnetic susceptibility is calculated. The spin correlation functions intra-plane and inter-plane have been also computed and compared with exchange couplings. The obtained theoretical results are in good agreement with experimental ones obtained by magnetic measurements and Mössbauer spectroscopy.


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Le document en format XML

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<title xml:lang="en" level="a">Magnetic properties and phase diagram of Zn
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Fe
<sub>2</sub>
O
<sub>4</sub>
: High-temperature series expansions</title>
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<term>Ferrites spinels</term>
<term>Iron Nickel Zinc Oxides Mixed</term>
<term>Magnetic susceptibility</term>
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<term>Effet Mössbauer</term>
<term>Loi Curie Weiss</term>
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<term>Exposant critique</term>
<term>Fer Nickel Zinc Oxyde Mixte</term>
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<front>
<div type="abstract" xml:lang="en">Using mean field theory and high-temperature series expansions (HTSEs), extrapolated with the Padé approximants method, the effect of Zn doping on magnetic properties of NiFe
<sub>2</sub>
O
<sub>4</sub>
ferrite spinel has been studied. The nearest neighbour super-exchange interactions for intra-site (J
<sub>AA</sub>
,J
<sub>BB</sub>
) and inter-site (J
<sub>AB</sub>
) of the Zn
<sub>x</sub>
Ni
<sub>1-x</sub>
Fe
<sub>2</sub>
O
<sub>4</sub>
ferrites spinels, in the range 0 ≤ x ≤ 1, have been computed using the probability approach, based on Mössbauer data. The paramagnetic Curie-Weiss temperature 0 and the Curie temperature T
<sub>C</sub>
are calculated as a function of Zn concentration. The critical exponent γ associated with magnetic susceptibility is calculated. The spin correlation functions intra-plane and inter-plane have been also computed and compared with exchange couplings. The obtained theoretical results are in good agreement with experimental ones obtained by magnetic measurements and Mössbauer spectroscopy.</div>
</front>
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